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by Allie Nicodemo
August 02, 2017
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Diamond electronics offer brilliant solutions

Diamonds are among the most coveted objects in the world. As gemstones, they are brilliant, rare and symbolic. As a raw material, they are a physicist’s best friend.

If you think about certain characteristics of a material – hardness, for example, or ability to conduct heat – diamonds are usually at one extreme end of the spectrum.

“It’s surprising that a material so simple, just carbon atoms arranged in this cubic crystal system, has such unusual properties in so many ways,” says Robert Nemanich, a Regents’ Professor of physics at Arizona State University.

As one of the world’s foremost experts on diamonds, Nemanich knows what they are capable of. And he’s got a different sort of proposal for how to use them.

A rose-cut synthetic diamond created by Apollo Diamond using a patented chemical vapour deposition process.
Photo by Steve Jurvetson, licensed under the Creative Commons Attribution 2.0 Generic license.

Doping diamonds for better electronics
Diamonds are the overachievers of the materials world. They can sustain incredibly high temperatures and electric fields. They also conduct heat better than any other material. These properties make them ideal for very specific applications.

Currently, silicon dominates the electronics market. It’s used to make everything from your cell phone computer chip and laptop processor to microwave ovens. But as versatile as silicon is, there are certain areas where it falls flat.

“When it comes to high-temperature, high-power, radiation-hard devices, silicon doesn’t work as well. In fact, it doesn’t work at all,” says Manpuneet Kaur Benipal, a post-doctoral researcher in Nemanich’s lab.

Benipal and her colleague Brianna Eller both received their PhDs from ASU. With Nemanich as an advisor, they are now starting a company, ADVENT Diamond, to make electronic devices out of diamond.

But we’re not talking about using recycled wedding rings. Eller and Benipal are working with doped diamond layers grown on small diamond plates. The ASU team even has a patent in the works for part of the growth process, called doping.

Watch the video at the top of the page to take a tour of Nemanich's lab and learn more about doping diamonds.

The term “doping” may conjure images of athletes illegally growing their muscles, but in the materials field, doping allows scientists to grow diamonds specifically for electronic purposes. Here’s how it works: you take a diamond substrate, or a small sample of diamond, and immerse it in a plasma composed of a mixture of chemicals. The atoms from the added chemicals organize themselves on the surface of the diamond, replicating the crystal structure of the substrate.

The lab-grown diamond layers that result include impurities that change the material’s electrical properties. Benipal and Eller use microfabrication processing of the doped diamond layers so that they behave precisely in the way they want. The process works so well that a small diamond can do the same work as materials that are much larger in size.

Does this mean we can expect to see tiny diamonds in our smartphones soon? Not exactly. Silicon continues to be more cost-effective for low-temperature applications, like cellphones and laptops. But diamond is a good choice for anything with a high-powered engine, such as an electric vehicle or an aircraft. Because diamond is excellent at conducting away heat, it would completely replace the need for a cooling system. Diamond also works well at very high pressures, which makes it perfect for deep-earth drilling.

More precise cancer treatment

We know diamonds’ ability to withstand extreme heat and pressure makes them superheroes in the world of electronic devices. But they have another power that scientists are harnessing to improve an entirely different field – cancer treatment.

Diamond is radiation-hard, meaning it takes much longer than most other materials to degrade under X-rays, gamma rays and fast charged particles. This property makes diamonds an ideal material to build radiation detectors for a variety of applications, including proton beam technology. This is a form of radiation therapy that precisely targets and destroys tumors with highly charged subatomic particles called protons.

Researchers at Nemanich’s lab, along with proton beam experts at Mayo Clinic Arizona, are working together to see if the use of diamond detectors can further enhance proton beam’s benefits to patients. Mayo Clinic is currently the only site in the southwest to offer the technology.

Mayo Clinic’s intensity-modulated proton beam therapy features pencil beam scanning, which deposits streams of protons back and forth through a tumor. The beam closely targets the tumor, while largely sparing surrounding healthy tissue and organs from its radiation.

The researchers are studying to see if diamonds can be used as a detector for the pencil beam to go through. This could possibly help radiation oncologists further fine tune the path of the protons, which could be particularly beneficial for pediatric patients.

“It’s most important in children to spare healthy tissues because those tissues are still growing, so we have to be very careful to treat as little of the healthy tissue as possible,” says Martin Bues, a proton beam physicist and researcher at Mayo Clinic’s Phoenix campus who is working with Nemanich and the ASU team on this project.

Robert Nemanich
ASU Regents’ Professor Robert Nemanich develops diamond wafers that provide an alternative to silicon for electronics that can function in high-temperature, high-pressure or radioactive environments.

A diamond in the sky
If diamond is a material superhero, perhaps it’s only fitting that scientists want to send it into space. Nemanich was recently awarded a grant from NASA to build diamond electronics for a rover that will explore the surface of Venus.

“Venus is 450 degrees centigrade,” Nemanich says, “So it’s very, very hot.”

How hot, exactly? To give you an idea, 450 degrees centigrade is about 842 degrees Fahrenheit. In comparison, the hottest weather ever recorded on Earth was a mere 129 degrees F, in Death Valley, CA in 2013.

Through the NASA grant, Nemanich and his team are building an amplifier, a device that increases the power of an electrical signal. But Eller says that diamond could be useful for other parts of the rover as well, since very few other materials can function in such extreme heat.

As demand for high-powered electronics increases, diamonds will have an even larger role to play. Space exploration, electronic vehicles and deep earth drilling only scratch the surface of potential applications.

Just as silicon brought about a new era of electronics, novel materials often drive the progress of new systems and devices. Perhaps the most exciting applications for diamonds are those that haven’t been thought of yet, since diamond would enable them to be built.

“There is always a need for something bigger, something better, something more efficient, something that works at higher temperature or higher voltage, which we think diamond can do,” Eller says.

The Department of Physics is a unit of the College of Liberal Arts and Sciences.